PUBLICATIONS

 

1.- P. Molina, A. Tárraga, A. Espinosa, M. Lorenzo-Peña, “Synthesis of Bridgehead-Nitrogen Heterocycles from Pyrylium Salts: Preparation of the Novel Tricyclic 1,3,4- Oxadiazino[2,3-c]pyrido[2,1-f][1,2,4]triazine Ring System” J. Chem. Res. (S), 1986, 460-461.

2.- P. Molina, A. Tárraga, M. Lorenzo-Peña, A. Espinosa, “Synthesis of Bridghead-Nitrogen Heterocycles from Pyrylium Salts: Preparation of the Novel Tricyclic Thiazolo[2,3-c]pyrido[2, 1-f][1,2,4]Triazine Ring System” Heterocycles, 1987, 26, 2183-2190.

3.- P. Molina, A. Tárraga, A. Espinosa, M. J. Lidón, “Oxamic Acid Derivatives in Heterocyclic Synthesis: Preparation of 1,4-Oxazine and 1,2,4-Triazino[5,6-e]-1,3,4-oxadiazine Derivatives” Synthesis,1987, 128-134. DOI: 10.1055/s-1987-27860.

4.- P. Molina, A. Tárraga, A. Espinosa, “Alkyl 2-Methyldithiocarbazates in heterocyclic Synthesis: Preparation of 2-alkylthio-1,3,4-thiadiazolium Cations and 2-Thioxo-2,3-dihydro-1,3,4-Oxadiazole Derivatives” Synthesis,1988, 690-693. DOI: 10.1055/s-1988-27672.

5.- P. Molina, A. Tárraga, A. Espinosa, “2-Metylthio-1,3,4-Thiadiazolium Cations as Useful Precursors for the Preparation of 2-Amino-1,3,4-thiadiazole Derivatives and as Dehydrating Reagents of Aldoximes” Heterocycles,1989, 29, 2301-2316.

6.- P. Molina, A. Tárraga, A. Espinosa, “Synthesis of 1,2,4-Triazole and 1,3,4-Thiadiazole Derivatives from Methyl 2-Methyldithiocarbazate and Heterocumulenes” Synthesis,1989, 923-929. DOI: 10.1055/s-1989-27431.

7.- P. Molina, A. Espinosa, A. Tárraga, F. Hernández-Cano, M. C. Foces-Foces, “Methyl 2-Methyldithiocarbazate in Heterocyclic Synthesis: Preparation of 2,5-Disubstituted 1,3,4-Thiadiazoles, Bis(1,3,4-Thiadiazolium) Salts and Macrocycles containing 1,3,4-Thiadiazole Subunits. X-Ray Crystal Structure of 2,2′-Bis[4,5-dihydro-5-(2-hydroxyethylimino)-4-methyl-1,3,4-thiadiazole” J. Chem. Soc. Perkin Trans. 1,1991, 1159-1166. DOI: 10.1039/p19910001159.

8.- P. Molina, A. Tárraga, I. Díaz, A. Espinosa, C. Gaspar, “Preparation of a Novel Type of Ligands Incorporating two or three 1,3,4-Thiadiazole Units” Heterocycles,1993, 36, 1263-1278.

9.- . Espinosa Ferao, B. Deschamps, F. Mathey, “Towards functional phospholide ions: synthesis of a 3-ethoxycarbonyl derivative” Bull. Soc. Chim. Fr.,1993, 130, 695-699.

10.- P. Molina, A. Tárraga, C. Gaspar, A. Espinosa, “Synthesis of a Novel Class of Macrocyclic Compounds containing 1,3,4-Thiadiazole Rings as Subunits” J. Org. Chem.,1994, 59, 3665-3669. DOI: 10.1021/jo00092a027.

11.- P. Nesvadba, D. Ngoc-Phan, F. Nydegger, A. Espinosa Ferao, A. Gossauer, “Synthesis of Bile Pigments. Part 18. Synthesis and Conformational Studies of Oxa- and Thia-deaza-biliverdin Analogues” Helv. Chim. Acta,1994, 77, 1837-1850. DOI: 10.1002/hlca.19940770715.

12.- P. Molina, A. Tárraga, M. J. del Baño, A. Espinosa, “Unexpected Triphenylphosphane-Promoted Conversion of 2-Azido-3-vinyl-1,4-naphthoquinones into 2-Amino-3-acyl-1,4-naphthoquinones” Liebigs Ann. Chem.,1994, 223-224. DOI: 10.1002/jlac.199419940220.

13.- A. Tárraga, P. Molina, J. L. López, A. Espinosa, D. J. Evans, “A new insight into the problem of stabilisation of alpha-carbocationic centres in the ferrocene series” Tetrahedron Lett.,2002, 43, 4117-4120. DOI: 10.1016/S0040-4039(02)00938-3.

14.- J. Pérez, L. García, E. Pérez, J. L. Serrano, J. F. Martínez, G. Sánchez, G. López, A. Espinosa, M. Liu, F. Sanz, “Solid state conformational and theoretical study of complexes containing the (CxN)Pd moiety (CxN = 2-(phenylazo)phenyl-C,N and its derivatives)” New J. Chem.,2003, 27, 1490-1496. DOI: 10.1039/b302653a.

15.- J. A. Ortuño, R. Expósito, C. Sánchez-Pedreño, M. I. Albero, A. Espinosa, “A nitrate-selective electrode based on a tris(2-aminoethyl)aminetriamide derivative receptor” Anal. Chim. Acta,2004, 525, 231-237. DOI: 10.1016/j.aca.2004.08.036.

16.- J. L. López, A. Tárraga. A. Espinosa, M. D. Velasco, P. Molina, V. Lloveras, J. Vidal-Gancedo, C. Rovira, J. Veciana, D. J. Evans, K. Wurst, “A new multifunctional ferrocenyl-substituted ferrocenophane derivative: ion-sensing, optical and electronic properties” Chem. Eur. J.,2004, 10, 1815-1826. DOI: 10.1002/chem.200305394.

17.- A. Tárraga, F. Otón, A. Espinosa, M. D. Velasco, P. Molina, D. J. Evans, “Synthesis and Properties of a New Class of Nitrogen-rich Multinuclear [m.n]Ferrocenophanes” Chem. Commun.,2004, 458-459. DOI: 10.1039/b313797j.

18.- F. Otón, A. Tárraga, M. D. Velasco, A. Espinosa, P. Molina, “A new fluoride selective electrochemical and fluorescent chemosensor based on a ferrocene–naphthalene dyad” Chem. Commun.,2004, 1658-1659. DOI: 10.1039/b404601c.

19.- A. Caballero, R. Tormos, A. Espinosa, M. D. Velasco, A. Tárraga, M. A. Miranda, P. Molina, “Selective Fluorescence Sensing of Li⁺ in an Aqueous Environment by a Ferrocene-Anthracene-Linked Dyad” Org. Letters,2004, 6, 4599-4602. DOI: 10.1021/ol047972m.

20.- A. Caballero, V. Lloveras, A. Tárraga, A. Espinosa, M. D. Velasco, J. Vidal-Gancedo, C. Rovira, K. Wurst, P. Molina, J. Veciana, “An Electroactive Nitrogen-Rich [4.4]Ferrocenophane Displaying Redox-Switchable Behavior: Selective Sensing, Complexation, and Decomplexation of Mg²⁺ ions” Angew. Chem. Int. Ed.,2005, 44, 1977-1981. DOI: 10.1002/anie.200462521.

21.- V. Lloveras, A. Caballero, A. Tárraga, M. D. Velasco, A. Espinosa, K. Wurst, D. J. Evans, J. Vidal-Gancedo, C. Rovira, P. Molina, J. Veciana, “Synthesis and Characterization of Radical Cations Derived from Mono- and Biferrocenyl-Substituted 2-Aza-1,3-butadienes: A Study of the Influence of an Asymmetric and Oxidizable Bridge on Intramolecular Electron Transfer” Eur. J. Inorg. Chem., 2005, 2436-2450. DOI: 10.1002/ejic.200400992.

22.- A. Espinosa, A. Frontera, R. García, M. A. Soler, A. Tárraga, “Electrophilic behavior of 3-methyl-2-methylthio-1,3,4-thiadiazolium salts: a multimodal theoretical approach” Arkivoc, 2005, ix, 415-437 (http://www.arkat-usa.org/get-file/19498/).

23.- A. Caballero, A. Tárraga, M. D. Velasco, A. Espinosa, P. Molina, “Multifunctional linear triferrocene derivatives linked by oxidizable bridges: optical, electronic and cation sensing properties” Org. Letters, 2005, 7, 3171-3174. DOI: 10.1021/ol050823z.

24.- F. Otón, A. Tárraga, A. Espinosa, M. D. Velasco, D. Bautista, P. Molina, “Preparation, Structure, and Anion Sensing Properties of 1,n-Diaza[n]ferrocenophanes” J. Org. Chem., 2005, 70, 6603-6608. DOI: 10.1021/jo050458p.

25.- R. Martínez, A. Espinosa, A. Tárraga, P. Molina, “New Hg²⁺ and Cu²⁺ Selective Cromo- and Fluoroionophore Based on a Bichromophoric Azine” Org. Letters, 2005, 7, 5869-5872. DOI: 10.1021/o1052508i.

26.- F. Otón, A. Tárraga, A. Espinosa, M. D. Velasco, P. Molina, “Ferrocene-Based Ureas as Multisignaling Receptors for Anions” J. Org. Chem., 2006, 71, 4590-4598. DOI: 10.1021/jo0604540.

27.- R. Martínez, F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “2-Aza-1,3-butadiene Derivatives Featuring an Anthracene or Pyrene Unit: Highly Selective Colorimetric and Fluorescent Signaling of Cu²⁺ Cation” Org. Letters, 2006, 8, 3235-3238. DOI: 10.1021/ol0610791.

28.- F. Otón, A. Tárraga, A. Espinosa, M. D. Velasco, P. Molina, “Heteroditopic ferrocene-based ureas as receptors for anions and cations” Dalton Trans., 2006, 3685-3692. DOI: 10.1039/b603544b.

29.- A. Caballero, V. Lloveras, D. Curiel, A. Tárraga, A. Espinosa, R. García, J. Vidal-Gancedo, C. Rovira, K. Wurst, P. Molina, J. Veciana, “Electroactive Thiazole Derivatives Capped with Ferrocenyl Units Showing Charge-Transfer Transition and Selective Ion-Sensing Properties: A Combined Experimental and Theoretical Study” Inorg. Chem., 2007, 46, 825-838. DOI: 10.1021/ic061803b.

30.- A. Caballero, R. García, A. Espinosa, A. Tárraga, P. Molina, “Multifunctional Ferrocene-Ruthenocene Dyads Linked by Single or Double Aza-Containing Bridges Displaying Metal-Metal Interactions and Cation Recognition Properties” J. Org. Chem.,2007, 72, 1161-1173. DOI: 10.1021/ja0618932.

31.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “A Simple but Effective Ferrocene Derivative as Redox, Colorimetric, and Fluorescent Receptor for Highly Selective Recognition of Zn²⁺ Ions” Org. Letters, 2007, 9, 2385-2388. DOI: 10.1021/ol070828r.

32.- F. Otón, A. Espinosa, A. Tárraga. C. Ramírez de Arellano, P. Molina, “[3.3]Ferro­cenophanes with Guanidine Bridging Units as Multisignalling Receptor Molecules for Selective Recognition of Anions, Cations and Amino Acids” Chem. Eur. J., 2007, 13, 5742-5752. DOI: 10.1002/chem.200601757.

33.- A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “Synthesis, Electrochemical and Optical Properties of Linear Homo- and Heterometallocene Triads” J. Org. Chem., 2007, 72, 6924-6937. DOI: 10.1021/jo071066g.

34.- H. Helten, C. Neumann, A. Espinosa, P. G. Jones, M. Nieger, R. Streubel, “Evidence for Ligand-Centered Reactivity of a 17e Radical Cationic 2H-Azaphosphirene Complex.” Eur. J. Inorg. Chem., 2007, 4669-4678. DOI: 10.1002/ejic.200700658.

35.- F. Otón, A. Espinosa, A. Tárraga, P. Molina, “Synthesis of Multifunctional Aza-Substituted Ruthenocene Derivatives Displaying Charge-Transfer Transitions and Selective Zn(II) Ions Sensing Properties.” Organometallics, 2007, 26, 6234-6242. DOI: 10.1021/om700757m.

36.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “Triple Channel Sensing of Pb(II) Ions by a Simple Multiresponsive Ferrocene Receptor Having a 1-Deazapurine Backbone.” Org. Letters, 2008, 10, 41-44. DOI: 10.1021/ol702541y.

37.- R. Martínez, A. Espinosa, A. Tárraga, P. Molina, “Bis(indolyl)methane derivatives as highly selective colorimetric and ratiometric fluorescent molecular chemosensors for Cu²⁺ cations” Tetrahedron, 2008, 64, 2184-2191. DOI: 10.1016/j.tet.2007.12.025.

38.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “Cation Coordination Induced Modulation of the Anion Sensing Properties of a Ferrocene−Imidazo­phenanthroline Dyad: Multichannel Recognition from Phosphate-Related to Chloride Anions” J. Org. Chem., 2008, 73, 4034-4044. DOI: 10.1021/jo800296c.

39.- A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “Ferrocene-Based Small Molecules for Dual-Channel Sensing of Heavy- and Transition-Metal Cations” J. Org. Chem., 2008, 73, 5489-5497. DOI: 10.1021/jo800709v.

40.- J. Pérez, A. Espinosa, J. M. Galiana, E. Pérez, J. L. Serrano, A. Cabeza, M. A. G. Aranda, “Crystal Packing in Di-(m-OH)-ortho-palladated Complexes – A DFT Insight into the Molecular Structure and Solid-State Interactions” Eur. J. Inorg. Chem., 2008, 3687-3697. DOI: 10.1002/ejic.200800383.

41.- >F. Otón, A. Espinosa, A. Tárraga, I. Ratera, K. Wurst, J. Veciana, P. Molina, “Mononuclear Ferrocenophane Structural Motifs with Two Thiourea Arms Acting as a Dual Binding Site for Anions and Cations” Inorg. Chem., 2009, 48, 1566-1576. DOI: 10.1021/ic801879x.

42.- T. Romero, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “A multiresponsive two-arm ferrocene-based chemosensor molecule for selective detection of mercury.” Dalton Trans., 2009, 2121-2129. DOI: 10.1039/b819778d.

43.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “A redox-fluorescent molecular switch based on a heterobimetallic Ir(III) complex with a ferrocenyl azaheterocycle as ancillary ligand” Dalton Trans., 2009, 3900-3902. DOI: 10.1039/b902055c.

44.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “Imidazole-Annelated Ferrocene Derivatives as Highly Selective and Sensitive Multichannel Chemical Probes for Pb(II) Cations” J. Org. Chem., 2009, 74, 4787-4796. DOI: 10.1021/jo900533x.

45.- H. Helten, S. Fankel, O. Feier-Iova, M. Nieger, A. Espinosa, R. Streubel, “Strong Evidence for an Unprecedented Borderline Case of Dissociation and Cycloaddition in Open-Shell 1,3-Dipole Chemistry: Transient Nitrilium Phosphane-Ylid Complex Radical Cations” Eur. J. Inorg. Chem., 2009, 3226-3237. DOI: 10.1002/ejic.200900314.

46.- J. Pérez, A. Espinosa, J. M. Galiana, E. Pérez, J. L. Serrano, M. A. G. Aranda, M. Insausti, “Orthogonal non-covalent binding forces in solid state supramolecular herringbone-shaped “interlocked dimers”. Pseudopolymorphism in [(ppy)Pd(µ-pz)]₂  (ppy = 2-(2-pyridyl)phenyl, pz = pyrazol-1-yl) complex” Dalton Trans., 2009, 9625-9636. DOI: 10.1039/b910502f.

47.- J. Ruiz, N. Cutillas, M. D. Villa, G. López, A. Espinosa, D. Bautista, “N1-Coordination in palladium(II) and platinum(II) complexes with 9-methylhypoxanthine: crystal structures and theoretical calculations”, Dalton Trans., 2009, 9637-9644. DOI: 10.1039/b915427b.

48.- D. Curiel, A. Espinosa, M. Mas-Montoya, G. Sánchez, A. Tárraga, P. Molina, “A new open benzodipyrrole-based chemosensor for hydrogenpyrophosphate anion in aqueous environment”, Chem. Commun., 2009, 7539-7541. DOI: 10.1039/b913345c.

49.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “A Selective Redox and Chromogenic Probe for Hg(II) in Aqueous Environment Based on a Ferrocene-Azaquinoxaline Dyad”, Inorg. Chem., 2009, 48, 11566-11575. DOI: 10.1021/ic901234d.

50.- R. Martínez, F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “2-Aza-1,3-butadiene ligands for the selective detection of Hg²⁺ and Cu²⁺ ion”, Arkivoc, 2010, iii, 124-144 (http://www.arkat-usa.org/get-file/28742/).

51.- F. Otón, I. Ratera, A. Espinosa, K. Wurtz, T. Parella, A. Tárraga, J. Veciana, P. Molina, “Selective Metal Cation Recognition by [2,2]Ferrocenophanes: The Cases of Zinc- and Lithium-Sensing”, Chem. Eur. J., 2010, 16, 1532-1542. DOI: 10.1002/chem.200901421.

52.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “A Selective Chromogenic and Fluorescent Molecular Probe for Yb(III) Based on a Bichromophoric Azadiene”, Eur. J. Inorg. Chem., 2010, 697-703. DOI: 10.1002/ejic.200901001.

53.- J. Pérez, E. Pérez, R. Carrascosa, A. Espinosa, L. García, J. L. Serrano, “Solid state conformational preferences of the {M(m-XPX)}₂ core (X = O, S) in transition metal complexes”, J. Molec. Struct., 2010, 968, 52-58. DOI: 10.1016/j.molstruc.2010.01.019.

54.- J. Ruiz, V. Rodríguez, C. de Haro, A. Espinosa, J. Pérez, C. Janiak, “New 7-azaindole palladium and platinum: crystal structures and theoretical calculations. In vitro anticancer activity of the platinum compounds”, Dalton Trans., 2010, 3290-3301. DOI: 10.1039/b920854b.

55.- A. Espinosa, R. García, M. A. López, P. Molina, A. Tárraga, “Unexpected Transalkylation on 3-Alkyl-2-alkylthio-1,3,4-thiadiazolium-5-thiolates: A Computational and Experimental Mechanistic Study”, Org. Biomol. Chem., 2010, 8, 1623-1628. DOI: 10.1039/b923243e.

56.- F. Otón, I. Ratera, A. Espinosa, A. Tárraga, J. Veciana, P. Molina, “Conformationally Modulated Intramolecular Electron Transfer Process in a Diaza [2.2]Ferrocenophane”, Inorg. Chem., 2010, 49, 3183-3191. DOI: 10.1021/ic902059y.

57.- R. Martínez, A. Espinosa, A. Tárraga, P. Molina, “A new bis(pyrenyl)azadiene-based probe for the colorimetric and fluorescent sensing of Cu(II) and Hg(II)”, Tetrahedron, 2010, 66, 3662-3667. DOI: 10.1016/j.tet.2010.03.080. Top 25 cited author for 2010-11

58.- F. Zapata, A. Caballero, A. Espinosa, A. Tárraga, P. Molina, “A multifaceted ferrocene-benzobisimidazole derivative: fluorogenic probe for Pb²⁺ and Zn²⁺ cations and unconventional fluorescence behaviour towards Cu²⁺ metal cations”, Dalton Trans., 2010, 39, 5429-5431. DOI: 10.1039/c001743d.

59.- C. Díez-Gil, R. Martínez, I. Ratera, T. Hirsh, A. Espinosa, A. Tárraga, P. Molina, O. S. Wolfbeis, J. Veciana, “Selective picomolar detection of mercury(II) using optical sensors”, Chem. Commun., 2011, 47, 1842-1844. DOI: 10.1039/c0cc04860g.

60.- J. Ruiz, V. Rodríguez, N. Cutillas, A. Espinosa, M. J. Hannon, “Novel C,N-Chelate Platinum(II) Antitumor Complexes Bearing a Lipophilic Ethisterone Pendant”, J. Inorg. Biochem., 2011, 105, 525-531. DOI: 10.1016/j.jinorgbio.2010.12.005.

61.- A. Espinosa, R. Streubel, “Computational studies on azaphosphiridines and the quest of how to effect ring-opening processes via selective bond activation”, Chem. Eur. J., 2011, 17, 3166-3178. DOI: 10.1002/chem.201002565.

62.- J. Ruiz, C. Vicente, C. de Haro, A. Espinosa, “Synthesis and Antiproliferative Activity of a C,N-Cycloplatinated(II) Complex with a Potentially Intercalative Anthraquinone Pendant” Inorg. Chem., 2011, 50, 2151-2158. DOI: 10.1021/ic101526h.

63.- M. Alfonso, A. Espinosa, A. Tárraga, P. Molina, “A Simple but Effective Dual Redox and Fluorescent Ion Pair Receptor Based on a Ferrocene−Imidazopyrene Dyad”, Org. Lett., 2011, 13, 2078-2081. DOI: 10.1021/ol2004935.

64.- T. Romero, R. Orenes, A. Espinosa, A. Tárraga, P. Molina, “Synthesis, Structural Characterization, and Electrochemical and Optical Properties of Ferrocene-Triazole-Pyridine Triads”, Inorg. Chem., 2011, 50, 8214-8224. DOI: 10.1021/ic200745q.

65.- J. Ruiz, V. Rodríguez, N. Cutillas, A. Espinosa, M. J. Hannon, “A Potent Ruthenium(II) Antitumor Complex Bearing a Lipophilic Levonorgestrel Group”, Inorg. Chem., 2011, 50, 9164-9171. DOI: 10.1021/ic201388n.

66.- A. Sola, F. Otón, A. Espinosa, A. Tárraga, P. Molina, “Aldimines generated from aza-Wittig reaction between bis(iminophosphoranes) derived from 1,1′-diazidoferrocene and aromatic or heteroaromatic aldehydes: electrochemical and optical behaviour towards metal cations”, Dalton Trans., 2011, 40, 12548-12559. DOI: 10.1039/c1dt11018g.

67.- F. Otón, M. C. González, A. Espinosa, A. Tárraga, P. Molina, “Synthesis, Structural Characterization, and Sensing Properties of Clickable Unsymmetrical 1,1′-Disubstituted Ferrocene−Triazole Derivatives”, Organometallics, 2012, 31, 2085-2096. DOI: 10.1021/om300093c.

68.- M. Alfonso, J. Contreras-García, A. Espinosa, A. Tárraga, P. Molina, “Highly selective mercury(II) cations detection in mixed–aqueous media by a ferrocene-based fluorescent receptor”, Dalton Trans., 2012, 41, 4437-4444. DOI: 10.1039/c2dt12156e.

69.- R. Streubel, J. M. Villalba Franco, G. Schnakenburg, A. Espinosa Ferao, “Reactivity of terminal phosphinidene versus Li/Cl phosphinidenoid complexes in cycloaddition chemistry. A case study”, Chem. Commun., 2012, 48, 5986-5988. DOI: 10.1039/c2cc31851b.

70.- M. Alfonso, A. Espinosa, A. Tárraga, P. Molina, “Multichannel HSO₄^– recognition promoted by a bound cation within a ferrocene-based ion pair receptor”, Chem. Commun., 2012, 48, 6848-6850. DOI: 10.1039/c2cc32215c.

71.- A. Espinosa, C. Gómez, R. Streubel, “Single electron transfer-mediated selective endo- and exocyclic bond cleavage processes in azaphosphiridine chromium(0) complexes: a computational study”, Inorg. Chem., 2012, 51, 7250-7256. DOI: 10.1021/ic300522g.

72.- D. Curiel, M. Más-Montoya, L. Usea, A. Espinosa, R. A. Orenes, P. Molina, “Indolocarbazole-based ligands for ladder type four-coordinate boron complexes”, Org. Lett., 2012, 14, 3360-3363. DOI: 10.1021/ol301339y.

73.- A. Espinosa, R. Streubel, “Exocyclic bond cleavage in oxaphosphirane complexes?”, Chem. Eur. J., 2012, 18, 13405-13411. DOI: 10.1002/chem.201201057.

74.- J. Ruiz, V. Rodríguez, N. Cutillas, K. G. Samper, M. Capdevila, O. Palacios, A. Espinosa, “Novel C,N-Chelate Rhodium(III) and Iridium(III) Antitumor Complexes Incorporating a Lipophilic Steroidal Conjugate and their interaction with DNA”, Dalton Trans., 2012, 41, 12847-12856. DOI: 10.1039/C2DT31654D.

75.- C. Schulten, G. von Frantzius, G. Schnakenburg, A. Espinosa, R. Streubel, “Deoxygenation of carbon dioxide by electrophilic terminal phosphinidene complexes”, Chem. Sci., 2012, 3, 3526-3533. DOI: 10.1039/C2SC21081A.

76.- T. Romero, A. Espinosa, A. Tárraga, P. Molina, “Multichannel recognition of hydrogen sulfate anion by a Zn(II)-triazole-pyridine complex bearing a ferrocenyl pendant”, Supramol. Chem., 2012, 24, 826-832. DOI: 10.1080/10610278.2012.721883.

77.- F. Otón, M. C. González, A. Espinosa, C. Ramírez de Arellano, A. Tárraga, P. Molina, “Ion-Pair Recognition Receptor Based on an Unsymmetrically 1,1´-Disubstituted Ferrocene-Triazole Derivative”, J. Org. Chem., 2012, 77, 10083-10092. DOI: 10.1021/jo301570u.

78.- V. Nesterov, G. Schnakenburg, A. Espinosa, R. Streubel, “Synthesis and reactions of the first room temperature stable Li/Cl phosphinidenoid complex”, Inorg. Chem., 2012, 51, 12343-12349. DOI:10.1021/ic301652u.

79.- D. Curiel, M. Más-Montoya, L. Usea, A. Espinosa, M. Allain, A. Fachetti, T. Marks, “Isomeric Carbazolocarbazoles: Synthesis, Characterization and Comparative Study in Organic Field Effect Transistors”, J. Mater. Chem. C, 2013, 1, 1959-1969. DOI: 10.1039/C2TC00363E.

80.- C. Albrecht, E. Schneider, M. Engeser, G. Schnakenburg, A. Espinosa, R. Streubel, “Synthesis and DFT Calculations of Spirooxaphosphirane Complexes”, Dalton Trans., 2013, 42, 8897-8906. DOI: 10.1039/C3DT50556A.

81.- S. Naskar, S. Naskar, R. Butcher, M. Corbella, A. Espinosa Ferao, S. K. Chattopadhyay, “Synthesis, X-ray crystal structures, spectroscopic, electrochemical and theoretical studies of Mn(III) complexes of pyridoxal Schiff bases with two diamines”, Eur. J. Inorg. Chem., 2013, 3249-3260. DOI: 10.1002/ejic.201300047.

82.- L. Abdrakhmanova, G. Schnakenburg, A. Espinosa, R. Streubel, “Reaction of Li/Cl phosphinidenoid complexes with a phosphite substituted ketone: access to complexes with a novel mixed-valence polycyclic P,C-ligand system”, Dalton Trans., 2013, 42, 10510-10514. DOI: 10.1039/C3DT50902H.

83.- A. Zamora, V. Rodríguez, N. Cutillas, G. S. Yellol, A. Espinosa, K. G. Samper, M. Capdevila, Ò. Palacios, J. Ruiz, “New Steroidal 7-Azaindole Platinum(II) Antitumor Complexes”, J. Inorg Biochem., 2013, 128, 48-56. DOI: 10.1016/j.jinorgbio.2013.07.010.

84.- A. Espinosa, F. Otón, R. Martínez, A. Tárraga, P. Molina, “A multidimensional undergraduate experiment for easy solution and surface sensing of Hg²⁺ and Cu²⁺ metal cations”, J. Chem. Educ., 2013, 90, 1057-1060. DOI: 10.1021/ed300571s.

85.- M. C. González, F. Otón, A. Espinosa, A. Tárraga, P. Molina, “A densely decorated disubstituted ferrocene as an ion-pair recognition receptor”, Chem. Commun., 2013, 49, 9633-9635. DOI: 10.1039/C3CC45707A.

86.- J. M. Villalba Franco, A. Espinosa Ferao, G. Schnakenburg, R. Streubel, “The azaphosphiridine to terminal phosphinidene complex rearrangement – looking for non-covalent interactions of a highly reactive species”, Chem. Commun., 2013, 49, 9648-9650. DOI: 10.1039/C3CC45477K.

87.- G. von Frantzius, A. Espinosa Ferao, R. Streubel, “Coordination of CO to low-valent phosphorus centres and other related P-C bonding situations. A theoretical case study”, Chem. Sci., 2013, 4, 4309-4322. DOI: 10.1039/C3SC52027G.

88.- G. Sánchez, A. Espinosa, D. Curiel, A. Tárraga, P. Molina, “Bis(carbazolyl)ureas as Selective Receptors for the Recognition of Hydrogenpyrophosphate in Aqueous Media”, J. Org. Chem., 2013, 78, 9725-9737. DOI: 10.1021/jo401430d.

89.- B. Ghosh, S. Naskar, S. Naskar, A. Espinosa, J. Yau, T. C. W. Mak, R. Sekiya, R. Kuroda, S. K. Chattopadhyay, “Heteroleptic Ru(II) complexes containing aroyl hydrazone and 2,2′-bipyridyl: Synthesis, X-ray crystal structures, electrochemical and DFT studies”, Polyhedron, 2014, 72, 115-121. DOI:  10.1016/j.poly.2014.01.031.

90.- L. Abdrakhmanova, G. Schnakenburg, A. Espinosa, R. Streubel, “The 3-acetyl-oxaphosphirane/1,3,2-dioxaphosphol-4-ene rearrangement”, Eur. J. Inorg. Chem., 2014, 10, 1727-1734. DOI: 10.1002/ejic.201301169.

91.- V. Nesterov, A. Espinosa, G. Schnakenburg, R. Streubel, “Novel N,P,C-cage complex via rearrangement of a tricyclic phosphirane complex. On the importance of non-covalent interactions” Chem. Eur. J., 2014, 20, 7010-7016. DOI: 10.1002/chem.201305061.

92.- M. C. González, F. Otón, R. A. Orenes, A. Espinosa, A. Tárraga, P. Molina, “Ferrocene-Triazole-Pyrene Triads as Multichannel Heteroditopic Recognition Receptors for Anions, Cations and Ion-Pairs”, Organometallics, 2014, 33, 2837-2852. DOI: 10.1021/om500358c.

93.- A. Espinosa, É. de las Heras, R. Streubel, “Oxaphosphirane-borane complexes: Ring strain and migratory insertion reactions” Inorg. Chem., 2014, 53, 6132-6140. DOI: 10.1021/ic500536h.

94.- J. Pérez, J. L. Serrano, I. da Silva, A. Espinosa, E. Pérez, L. García, “Ligands hierarchy on driving the crystal packing. Insight into solid state saccharinate Pd(II) complexes” Cryst. Eng. Comm., 2014, 16, 7124-7132. DOI: 10.1039/C4CE00518J.

95.- A. Sola, A. Espinosa, A. Tárraga, P. Molina, “Nitrogen-Rich Multinuclear Ferrocenophanes as Multichannel Chemosensor Molecules for Transition and Heavy-Metal Cations” Sensors, 2014, 14, 14339-14355. DOI: 10.3390/s140814339.

96.- A. Espinosa, L. Abdrakhmanova, R. Streubel, “Theoretical study on novel mixed-valence, P-H-functional P-ligands and their tautomerization” Heteroatom Chem., 2014, 25, 643-657. DOI: 1002/hc.21207.

97.- M. Alfonso, A. Espinosa, A. Tárraga, P. Molina, “Multifunctional Benzothiadiazole-based Small Molecules Displaying Solvatochromism and Sensing Properties toward Nitroarenes, Anions and Cations” Chemistry Open, 2014, 3, 242-249. DOI: 10.1002/open.201402022.

98.- S. Ahmad, A. Espinosa, T. Ahmad, M. Sohail, A. A. Isab, M. Saleem, A. Hameed, M. Monim-ul-Mehboob, É. de las Heras, “Synthesis, theoretical calculations and antimicrobial studies of copper(I) complexes of cysteamine, cysteine and 2-mercaptonicotinic acid” Polyhedron, 2015, 85, 239-245. DOI: 10.1016/j.poly.2014.08.029.

99.- H. Sadaf, A. A. Isab, S. Ahmad, A. Espinosa, M. Más-Montoya, I. U. Khan, Ejaz, S.-U. Rehman, M. A. J. Ali, M. Saleem, J. Ruiz, C. Janiak, “Synthesis, crystal structure, theoretical calculations and antimicrobial properties of [Pt(tetramethylthiourea)4] [Pt(CN)4]•4H2O” J. Molec. Struct., 2015, 185, 155-161. DOI: 10.1016/j.molstruc.2014.12.076.

100.- M. C. González, F. Otón, A. Espinosa, A. Tárraga, P. Molina, “Tris(triazole) tripodal receptors as selective probes for citrate anion recognition and multichannel transition and heavy metal cations sensing” Org. Biomol. Chem, 2015, 13, 1429-1438. DOI: 10.1039/C4OB02135E.

101.- J. M. Villalba Franco, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Unprecedented ring/ring interconversion of N,P,C-cage ligands” Chem. Eur. J., 2015, 21, 3727-3735. DOI: 10.1002/chem.201405754.

102.- J. M. Villalba Franco, T. Sasamori, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their surprising conversion into oxaphosphirane complex valence isomers” Chem. Commun., 2015, 51, 3878-3881. DOI: 10.1039/C4CC10266E.

103.- A. Espinosa, M. Sohail, M. Habib, K. Naveed, M. Saleem, H. Rehman, I. Hussain, A Munawar, S. Ahmad, “Synthesis, crystal structure, theoretical calculations, and electrochemical and biological studies of polymeric (N,N,N’,N’-tetramethylethylenediamine)bis(thiocyanato-N)copper(II), [Cu(tmeda)(NCS)2]n” Polyhedron, 2015, 90, 252-257. DOI: 10.1016/j.poly.2015.02.017.

104.- C. Franco, M. Mas-Torrent, A. Caballero, A. Espinosa, P. Molina, J. Veciana, C. Rovira, “A pyrene based dyad and triad leading to a reversible chemical and redox optical and magnetic switch with potential for logic gates” Chem. Eur. J., 2015, 21, 5504-5509. DOI: 10.1002/chem.201405993.

105.- R. Streubel, A. Espinosa, C. Murcia García, G. Schnakenburg, “Evidence for terminal phosphinidene oxide complexes in the O,P,C-cage complex formation: rearrangement of oxaphosphirane complexes” Organometallics, 2015, 34, 2676-2682. DOI: 10.1021/acs.organomet.5b00029.

106.- A. Antiñolo, S. García-Yuste, A. Otero, A. Espinosa, “An Unusual Mechanism for the Reaction of a Hydrideniobocene Complex with Activated Alkynes. Experimental and DFT Studies” Organometallics,  2015, 34, 2695-2698. DOI: 10.1021/om5010989.

107.- J. M. Villalba Franco, G. Schnakenburg, T. Sasamori, A. Espinosa Ferao, R. Streubel, “Substrate stimuli-responsive FLP-type reactivity – first insights” Chem. Eur. J., 2015, 21, 9650-9655. DOI: 10.1002/chem.201501628..

108.- R. Streubel, J. Faßbender, G. Schnakenburg, A. Espinosa Ferao, “Formation of transient and stable 1,3-dipole complexes with P,S,C and S,P,C ligand skeletons” Organometallics, 2015, 34, 3103-3106. DOI: 10.1021/acs.organomet.5b00386.

109.- M. Alfonso, A. Espinosa, A. Tárraga, P. Molina, “Electrochemical and Fluorescent Ferrocene-Imidazole-Based Dyads as Ion-Pair Receptors for Divalent Metal Cations and Oxoanions” Inorg. Chem., 2015, 54, 7461-7473. DOI: 10.1021/acs.inorgchem.5b01071.

110.- J. Yellol, S. A. Pérez, A. Buceta, G. Yellol, A. Donaire, P. Szumlas, P. J. Bednarski, G. Makhloufi, C. Janiak, A. Espinosa, J. Ruiz, “Novel C,N-cyclometalated Benzimidazole Ruthenium(II) and Iridium(III) Complexes as Antitumor and Antiangiogenic Agents: a Structure-Activity Relationship Study” J. Med. Chem., 2015, 58, 7310-7327. DOI: 10.1021/acs.jmedchem.5b01194.

111.- M. Klein, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Rearrangement and deoxygenation of 3,3-bis(2-pyridyl)oxaphosphirane complexes” Dalton Trans., 2016, 45, 2085-2094. DOI: 10.1039/C5DT03404C.

112.- C. Murcia García, A. Espinosa Ferao, G. Schnakenburg, R. Streubel, “CPh₃ as a functional group in P-heterocyclic chemistry: elimination of HCPh₃ in the reaction of P-CPh₃ substituted Li/Cl phosphinidenoid complexes with Ph₂CO” Dalton Trans., 2016, 45, 2378-2385. DOI: 10.1039/c5dt04595a.

113.- M. Klein, G. Schnakenburg, A. Espinosa Ferao, N. Tokitoh, R. Streubel, “Surprising entries to NHC adducts of terminal phosphinidene complexes including an unprecedented oxaphosphirane complex conversion” Eur. J. Inorg. Chem., 2016, 685-690. DOI: 10.1002/ejic.201500959.

114.- A. Espinosa Ferao, F. Afzal, S. Aslam, I. K. Muhammad, Ejaz, I. U. Khan, M. Fettouhi, A. A. Isab, S. Ahmad, “Synthesis, Crystal structure and DFT Calculations of Bis(1,3-diazinane-2-thione-κS)dicyanido disilver(I), [{Ag(Diaz)2}{Ag(CN)2}]” Polyhedron, 2016, 110, 299-304. DOI: 10.1016/j.poly.2015.10.028.

115.- M. Más-Montoya, L. Usea, A. Espinosa Ferao, M. F. Montenegro, C. Ramírez de Arellano, A. Tárraga, J. N. Rodríguez-Lopez, D. Curiel, “Single heteroatom fine tuning of the emissive properties in organoboron complexes with 7-(azaheteroaryl)indole systems” J. Org. Chem., 2016, 81, 3296-3302. DOI: 10.1021/acs.joc.6b00265.

116.- M. D. Santana, L. López-Banet, G. Sánchez, E. Pérez, L. García, J. L. Serrano, A. Espinosa, “Non-covalent stacking interactions directing the structural and photophysical features of mono- and dinuclear cyclometallated palladium(II) complexes” Dalton Trans., 2016, 45, 8601-8613. DOI: 10.1039/C5DT04913J.

117.- J. M. Villalba Franco, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Unveiling new features of the coordination chemistry of a non-metal element – the case of 3-imino-azaphosphiridine complexes” Dalton Trans., 2016, 45, 13951-13956. DOI: 10.1039/C6DT02909D.

118.- P. Malik, A. Espinosa Ferao, G. Schnakenburg, R. Streubel, “Cycloaddition of P-C single bonds. Stereoselective formation of novel benzo-1,3,6,2-trioxaphosphepine complexes via a ditopic van der Waals complex” Angew. Chem. Int. Ed., 2016, 55, 12693-12697. DOI: 10.1002/anie.201606264.

119.- A. Espinosa Ferao, R. Streubel, “Thiaphosphiranes and their complexes: systematic study on ring strain and ring cleavage reactions” Inorg. Chem., 2016, 55, 9611-9619. DOI: 10.1021/acs.inorgchem.6b01322.

120.- T. Sasamori, T. Sugahara, J.-D. Guo, Y. Karatsu, Y. Furukawa, A. Espinosa Ferao, S. Nagase, N. Tokitoh, “Reaction of a Diaryldigermyne with Acetylenes: Synthesis of a 1,2-Digermabenzene and a 1,4-Digermabarrelene” Bull. Chem. Soc. Jpn., 2016, 89, 1375-1384. DOI: 10.1246/bcsj.20160269. Awarded article!

121.- A. Espinosa Ferao, “Kinetic energy density per electron as quick insight into ring strain energies” Tetrahedron Lett., 2016, 57, 5616-5619. DOI: 10.1016/j.tetlet.2016.10.115.

122.- A. Espinosa Ferao, R. García, “Fulvenization as characteristic geometric distortion in electron deficient ferrocenes” Tetrahedron, 2017, 73, 952-956. DOI: 10.1016/j.tet.2017.01.019.

123.- S. Sagar, S. Sengupta, S. K. Chattopadhyay, A. J. Mota, A. Espinosa Ferao, E. Riviere, W. Lewis, S. Naskar, “Cubane-like tetranuclear Cu(II) complexes bearing a Cu4O4 core: crystal structure, magnetic properties, DFT calculations and phenoxazinone synthase like activity” Dalton Trans., 2017, 46, 1249-1259. DOI: 10.1039/C6DT03754B.

124.- A. Espinosa Ferao, R. García, “The structure of Cu(II) and Hg(II) complexes of bispyrenyl azine revisited” J. Mol. Model., 2017, 23, 124. DOI: 10.1007/s00894-017-3296-x.

125.- A. Espinosa Ferao, R. Streubel, “A computational study on the stability of oxaphosphirane rings towards closed-shell valence isomerization” Eur. J. Inorg. Chem, 2017, 2702-2712. DOI: 10.1002/ejic.201700177.

126.- A. Espinosa Ferao, R. Streubel, “Coordination of N2 and other small molecules to the phosphorus center of RPW(CO)5 – A theoretical study on the Janus facets of the stabilization/activation problem” Chem. Eur. J., 2017, 23, 8632-8643. DOI: 10.1002/chem.201700524. Hot paper !

127.- A. Espinosa Ferao, “Comparative computational study on the reaction of chloroacetone with trimethylphosphite: Perkow versus Michaelis-Arbuzov reaction paths” J. Phys. Chem. A, 2017, 121, 6517-6522. DOI: 10.1021/acs.jpca.7b06262.

128.- A. Parween, S. Naskar, A. J. Mota , A. Espinosa Ferao, S. K. Chattopadhyay, E. Riviere, W. Lewis, S. Naskar, “Ci-symmetry, [2 × 2] grid, square copper complex with the N4,N5-bis(4-fluorophenyl)-1H-imidazole-4,5-dicarboxamide ligand: structure, catecholase activity, magnetic properties and DFT calculations” New J. Chem., 2017, 41, 11750-11758. DOI: 10.1039/C7NJ01667K.

129.- J. Faßbender, N. Künemund, A. Espinosa Ferao, G. Schnakenburg, R. Streubel, “Epoxide-like chemistry: 1,2-bifunctional P-ligands via stereo- and regioselective ring opening of an oxaphosphirane complex” Organometallics, 2018, 37(8), 1331-1336. DOI: 10.1021/acs.organomet.8b00116.

130.- A. W. Kyri, F. Gleim, A. García Alcaraz, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, ““Low-coordinate” 1,2-oxaphosphetanes – a new opportunity in coordination and main group chemistry” Chem Commun., 2018, 54(52), 7123-7126. DOI: 10.1039/C8CC02963F. Front cover !

131.- A. Espinosa Ferao, , “On the mechanism of trimethylphosphine-mediated reductive dimerization of ketones” Inorg. Chem., 2018, 57(14), 8058-8064. DOI: 10.1021/acs.inorgchem.7b02816.

132.- J. Faßbender, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Effects of diminished steric protection at phosphorus on stability and reactivity of oxaphosphirane complexes” Dalton Trans., 2018 47(28), 9347-9354. DOI: 10.1039/C8DT01979G.

133.- J. Faßbender, G. Schnakenburg, D. P. Gates, A. Espinosa Ferao, R. Streubel, “Unconventional ionic ring-deconstruction pathways of a three-membered heterocycle” Chem. Commun., 2018, 54(99), 14013-14016. DOI: 10.1039/c8cc08713j.

134.- A. Rey, A. Espinosa Ferao, R. Streubel, “Quantum Chemical calculations on CHOP derivatives – spanning the chemical space of phosphinidenes, phosphaketenes, oxaphosphirenes and COP‾ isomers” Molecules, 2018, 23(12), 3341. DOI: 10.3390/molecules23123341.

135.- A. Schmer, N. Volk, A. Espinosa Ferao, R. Streubel, “Access and unprecedented reaction pathways of Li/Cl phosphinidenoid iron(0) complexes” Dalton Trans., 2019, 48(1), 339-345. DOI: 10.1039/C8DT04417A.

136.- A. W. Kyri, F. Gleim, D. Becker, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands” Chem. Commun., 2019, 55(11), 1615-1618. DOI: 10.1039/C8CC09892A.

137.- A. Schmer, T. Terschüren, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Access to 1,1’-bifunctional phosphane iron(0) complexes via P-N bond forming reactions and selective P-functionalisations” Eur. J. Inorg. Chem., 2019, 1604-1611. DOI: 10.1002/ejic.201801065. Very Important Paper !

138.- A. Khan, P. Junker, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Competitive or sequential reaction of an electrophilic terminal phosphinidene metal(0) complex with allyl halides? [2+1]-Cycloaddition vs C-X bond insertion” Chem. Commun., 2019, 55(11), 9987-9990. DOI: 10.1039/C9CC05328J.

139.- V. Nesterov, R. Baierl, F. Hanusch, A. Espinosa Ferao, S. Inoue, “NHC-Stabilized Germanium and Tin Analogues of Heavier Nitriles: Synthesis, Reactivity, and Catalytic Application” J. Am. Chem. Soc., 2019, 141(37), 14576-14580. DOI: 10.1021/jacs.9b08741.

140.- A. Espinosa Ferao, R. Streubel, “1,2-Thiaphosphetanes: The quest for Wittig-type ring cleavage, rearrangement and sulfur atom transfer” Inorg. Chem., 2020, 59(5), 3110-3117. DOI: 10.1021/acs.inorgchem.9b03471.

141.- R. Kunzmann, Y. Omatsu, G. Schnakenburg, A. Espinosa Ferao, T. Yanagisawa, N. Tokitoh, R. Streubel, “A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si-Cl function” Chem. Commun., 2020, 56, 3899-3902. DOI: 10.1039/D0CC00024H.

142.- M. Más-Montoya, M. F. Montenegro, A. Espinosa Ferao, A. Tárraga, J. N. Rodriguez-Lopez, D. Curiel, “Rigid π-Extended Boron Difluoride Complex with Mega-Stokes Shift for Bioimaging” Org. Lett., 2020, 22(9), 3356-3360. DOI: 10.1021/acs.orglett.0c00782.

143.- A. Espinosa Ferao, A. García Alcaraz, “Benchmarking the inversion barriers in σ³λ³-phosphorus compounds: a computational study” New J. Chem., 2020, 44, 8763-8770. DOI: 10.1039/D0NJ01237H.

144.- T. Sugahara, A. Espinosa Ferao, A. Rey Planells, J.-D. Guo, S. Aoyama, K. Igawa, K. Tomooka, T. Sasamori, D. Hashizume, S. Nagase, N. Tokitoh, “1,2-Insertion Reactions of Alkynes into Ge–C Bonds of Arylbromogermylene” Dalton Trans., 2020, 49, 7189-7196. DOI: 10.1039/D0DT01223H.

145.- A. Rey Planells, A. Espinosa Ferao, “Accurate ring strain energy calculations on saturated three-membered heterocycles with one group 13-16 element” Inorg. Chem., 2020, 59, 11503-11513. DOI: 10.1021/acs.inorgchem.0c01316.

146.- A. Espinosa Ferao, A. García Alcaraz, S. Zaragoza Noguera, R. Streubel “Terminal phosphinidene complex adducts with neutral and anionic O-donors and halides, and the search for a differentiating bonding descriptor” Inorg. Chem., 2020, 59, 12829-12841. DOI: 10.1021/acs.inorgchem.0c01874.

147.- A. Gese, M. Akter, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “P-Functional tetrathiafulvalenes from 1,3-dithiole-2-thiones?” New J. Chem., 2020, 44, 17122-17128. DOI: 10.1039/D0NJ02984J.

148.- R. Streubel, N. Volk, G. Schnakenburg, A. García Alcaraz, A. Espinosa Ferao, “Synthesis of the first oxaphosphirane iron complexes” Eur. J. Inorg. Chem., 2021, 22(3), 252-257. DOI: 10.1002/ejic.202000812.

149.- P. Junker, Z.-W. Qu, T. Kalisch, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “A case study on the conversion of Li/Cl phosphinidenoid into phosphinidene complexes” Dalton Trans., 2021, 50, 739-745. DOI: 10.1039/D0DT03884A.

150.- A. Espinosa Ferao, A. Rey Planells, R. Streubel, “Between oxirane and phosphirane: the spring loaded oxaphosphirane ring” Eur. J. Inorg. Chem., 2021, 22, 348-353. DOI: 10.1002/ejic.202000881.

151.- A. Espinosa Ferao, A. García Alcaraz, R. García López, “Electronic structure and bridge geometric distortion in push-pull imine-bridged triads. A theoretical study” New J. Chem., 2021, 45, 4472-4480. DOI: 10.1039/D1NJ00152C.

152.- N. Volk, P. Malik, A. García Alcaraz, A. Espinosa Ferao, R. Streubel, “Chemistry of Oxaphosphirane Complexes” Coord. Chem. Rev., 2021, 437, 213818. DOI: 10.1016/j.ccr.2021.213818.

153.- A. Schmer, P. Junker, A. Espinosa Ferao, R. Streubel, “M/X Phosphinidenoid Metal Complex Chemistry” Acc. Chem. Res., 2021, 54(7), 1754-1765. DOI: 10.1021/acs.accounts.1c00017.

154.- A. García Alcaraz, A. Espinosa Ferao, R. Streubel, “Azaphosphiridines: Challenges and perspectives” Dalton Trans., 2021, 50, 7324-7336. DOI: 10.1039/D1DT01174J.

155.- P. Junker, A. Rey Planells, A. Espinosa Ferao, R. Streubel, “Analysis of non-innocence of phosphaquinodimethane ligands when charge and aromaticity come into play” Chem. Eur. J., 2021, 27, 9350-9359. DOI: 10.1002/chem.202100420.

156.- A. Gese, S. Kermanshashian, G. Schnakenburg, Z. Kelemen, L. Nyulaszi, A. Espinosa Ferao, R. Streubel, “Towards a 1,4-diphosphinine-based molecular CPS-ternary compound” Inorg. Chem., 2021, 60(17), 13029-13040. DOI: 10.1021/acs.inorgchem.1c01463.

157.- A. Schmer, A. García Alcaraz, A. W. Kyri, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Synthesis of azadiphosphiridine complexes. Theoretical studies on ring formation, the P-to-P′ metal shift and the resulting nitrogen geometry” Dalton Trans., 2022, 51, 3275-3279. DOI: 10.1039/D1DT04252A.

158.- A. Rey Planells, A. Espinosa Ferao, “CHNO isomers and derivatives – A computational overview” New J. Chem., 2022, 46, 5771-5778. DOI: 10.1039/D1NJ05752A.

159.- A. Rey Planells, A. Espinosa Ferao, “Accurate Ring Strain Energies of Unsaturated Three-Membered Heterocycles with One Group 13−16 Element” Inorg. Chem., 2022, 61(17), 6459-6468. DOI: 10.1021/acs.inorgchem.2c00067.

160.- F. Gleim, A. García Alcaraz, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “1,2σ3λ3-Oxaphosphetanes and Their P-Chalcogenides – A Combined Experimental and Theoretical Study” Molecules, 2022, 27(10), 3345. DOI: 10.3390/molecules27103345.

161.- T. Terschüren, P. Junker, A. Schmer, A. Espinosa Ferao, R. Streubel, “Regioselective N- versus P-deprotonation of amino-phosphane tungsten(0) complexes” Organics, 2022, 3(3), 161-172. DOI: 10.3390/org3030013.

162.- A. Rey Planells, A. Espinosa Ferao, “Ring Strain Energies of Three-membered Homoatomic Inorganic rings El3 and Diheterotetreliranes El2Tt (Tt = C, Si, Ge). Accurate versus Additive Approaches” Inorg. Chem., 2022, 61(35), 13846-13857. DOI: 10.1021/acs.inorgchem.2c01777.

163.- M. Más-Montoya, A. García Alcaraz, A. Espinosa Ferao, D. Bautista, D. Curiel, “Insight into the Stokes shift, divergent solvatochromism and aggregation-induced emission of boron complexes with locked and unlocked benzophenanthridine ligands” Dyes&Pigments, 2022, 209(B), 110924. DOI: 10.1016/j.dyepig.2022.110924.

164.- J. Faßbender, N. Volk, A. García Alcaraz, A. Espinosa Ferao, R. Streubel “The quest for unligated oxaphosphiranes with phosphorus in different coordination numbers” Chem. Commun., 2022, 59(10), 1285-1288. DOI: 10.1039/D2CC05730A.

165.- A. A. Khan, T. Kalish, A. Espinosa Ferao, R. Streubel, “Dehydrogenation reaction of triethylamine by an electrophilic terminal phosphinidene complex” Dalton Trans., 2023, 52, 3275-3278. DOI: 10.1039/D3DT00300K.

166.- M. Ludwig, D. Franz, A. Espinosa Ferao, M. Bolte, F. Hanusch, S. Inoue, “Anions featuring an aluminium–silicon core with alumanyl silanide and aluminata-silene characteristics” Nat. Chem., 2023, 15, 1452-1460, DOI: 10.1038/s41557-023-01265-3.

167.- D. Biskup, G. Schnakenburg, R. T. Boeré, A. Espinosa Ferao, R. Streubel, “A novel access to phosphanylidene-phosphorane complexes via P-donor substitution and a detailed bonding analysis”, Dalton Trans., 2023, 52, 13781-13786, DOI: 10.1039/D3DT02304D.

168.– D. Biskup, G. Schnakenburg, R. T. Boeré, A. Espinosa Ferao, R. K. Streubel, “Challenging an old paradigm: coordination and organometallic chemistry of a neutral nonmetal ligand center”, Nat. Commun., 2023, 14, 6456, DOI 10.1038/s41467-023-42127-3.

169.– A. Espinosa Ferao, A. Rey Planells, “Ring Strain Energy of Diheteropnictogeniranes El₂Pn (Pn = N, P, As, Sb) – Accurate versus Additive Approaches”, Chem. Eur. J., 2023, 29, e202302243, DOI: 10.1002/chem.202302243.

170.- D. Biskup, G. Schnakenburg, A. Espinosa Ferao, R. K. Streubel, “Access to ligand-stabilized PH-containing phosphenium complexes”, Dalton Trans., 2024, 53, 2517-2525, DOI: 10.1039/D3DT03869F.

171.- A. Espinosa Ferao, “Deoxygenation of Oxiranes by λ³σ³-Phosphorus Reagents – Computational Mechanistic and Stereochemical Study”, ChemPlusChem, 2024, DOI: 10.1002/cplu.202300474.

172.- A. Espinosa Ferao, “Carbonylation of Boranes – A Computational Study”, Eur. J. Inorg. Chem., 2024, DOI: 10.1002/ejic.202300641.

173.- F. Gleim, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Arbuzov meets 1,2-oxaphosphetanes: transient 1,2-oxaphosphetan-2-iums as entry point to beta-halo phosphane oxides and P-containing oligomers”, Chem. Commun., 2024, accepted, DOI: 10.1039/D4CC00254G.

174.- A. Rey Planells, A. Espinosa Ferao, R. Streubel, A. Frontera, “Internal Coulombic Assistance in Intermolecular Frustrated Lewis Pair Activation of Dihydrogen”, New J. Chem., 2024, accepted, DOI: 10.1039/D4NJ00523F.

175.- A. Espinosa Ferao, A. García Alcaraz, “The inversion mechanism in σ³λ³-pnictogen compounds: chemical bonding analysis and periodic trends” submitted .

 

updated 22.02.2024