2012

Insertion of Allenes into the Pd-C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (L)-Phenylalanine Methyl Ester, and (L)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts

García-López, J. A.; Saura-Llamas, I.; McGrady, J. E.; Bautista, D.; Vicente, J. Organometallics 2012, 31, 8333.

http://dx.doi.org/10.1021/om300928j

 

From Chelate C,N-Cyclopalladated Oximes to C,N,N ‘-, C,N,S-, or C,N,C ‘-Pincer Palladium(II) Complexes by Formation of Oxime Ether Ligands

Abellán-López, A.; Chicote, M. T.; Bautista, D.; Vicente, J. Organometallics 2012, 31, 7434.

http://dx.doi.org/10.1021/om3007213

 

The First Complexes with Two Metallacycles Fused Around a Common Aryl Substituent: “Akimbo” Complexes

Chicote, M. T.; Vicente-Hernández, I.; Jones, P. G.; Vicente, J. Organometallics 2012, 31, 6252.

http://dx.doi.org/10.1021/om300545k

 

Reactivity toward CO of Eight-Membered Palladacycles Derived from the Insertion of Alkenes into the Pd-C Bond of Cyclopalladated Primary Arylalkylamines of Pharmaceutical Interest. Synthesis of Tetrahydrobenzazocinones, Ortho-Functionalized Phenethylamines, Ureas, and an Isocyanate

García-López, J. A.; Oliva-Madrid, M. J.; Saura-Llamas, I.; Bautista, D.; Vicente, J. Organometallics 2012, 31, 6351.

http://dx.doi.org/10.1021/om300593x

 

Dinuclear Alkynyl Gold(I) Complexes Containing Bridging N-Heterocyclic Dicarbene Ligands: New Synthetic Routes and Luminescence

Gil-Rubio, J.; Cámara, V.; Bautista, D.; Vicente, J. Organometallics 2012, 31, 5414.

http://dx.doi.org/10.1021/om300431r

 

Providing Support in Favor of the Existence of a PdII/PdIV Catalytic Cycle in a Heck-Type Reaction

Juliá-Hernández, F.; Arcas, A.; Vicente, J. Chem. Eur. J. 2012, 18, 7780.

http://dx.doi.org/10.1002/chem.201103679

 

Ortho Palladation of the Phenethylamines of Biological Relevance L-Tyrosine Methyl Ester and Homoveratrylamine. Reactivity of the Palladacycles toward CO and Isocyanides. Synthesis of the Natural Alkaloid Corydaldine

Oliva-Madrid, M. J.; García-López, J. A.; Saura-Llamas, I.; Bautista, D.; Vicente, J. Organometallics 2012, 31, 3647.

http://dx.doi.org/10.1021/om300141b

 

Synthesis of Palladium(II), -(III), and -(IV) Complexes with Acyclic Diaminocarbene Ligands

Martínez-Martínez, A. J.; Chicote, M. T.; Bautista, D.; Vicente, J. Organometallics 2012, 31, 3711.

http://dx.doi.org/10.1021/om300201s

 

Synthesis and Hydrolysis of Cationic Palladium(II) 2,6-Diacetylpyridine Dimethyl Ketal Complexes. Cyclopalladation of 2,6-Diacetylpyridine. Palladium-Catalyzed Synthesis of a 1,5-Benzodiazepine

Juliá-Hernández, F.; Arcas, A.; Bautista, D.; Vicente, J. Organometallics 2012, 31, 3736.

http://dx.doi.org/10.1021/om300217k

 

Synthesis and Photophysical Properties of Cyclometalated Platinum(II) 1,2-Benzenedithiolate Complexes and Heterometallic Derivatives Obtained from the Addition of (Au(PCy3) (+) Units

Juliá, F.; Jones, P. G.; González-Herrero, P. Inorg. Chem. 2012, 51, 5037.

http://dx.doi.org/10.1021/ic202465k

 

Sequential Insertion of Alkynes and CO or Isocyanides into the Pd-C Bond of Cyclopalladated Phenylacetamides. Synthesis of Eight-Membered Palladacycles, Benzo d azocine-2,4(1H,3H)-diones, and Highly Functionalized Acrylonitrile and Acrylamide Derivatives

Frutos-Pedreño, R.; González-Herrero, P.; Vicente, J.; Jones, P. G. Organometallics 2012, 31, 3361.

http://dx.doi.org/10.1021/om300151n

 

Synthesis and Reactivity of PdCl2{C,N-C6H4C(=NHXy)NH2-2} and Neutral Palladium 1,2-Dihydroquinazolinium-4-yl Complexes: Depalladation Reactions

Martínez-Martínez, A. J.; Vicente, J.; Chicote, M. T.; Bautista, D. Organometallics 2012, 31, 2697.

http://dx.doi.org/10.1021/om200986k

 

Reactions of Half-Sandwich Ethene Complexes of Rhodium(I) toward lodoperfluorocarbons: Perfluoro-alkylation or -arylation of Coordinated Ethene versus Oxidative Addition

Gil-Rubio, J.; Guerrero-Leal, J.; Blaya, M.; Vicente, J.; Bautista, D.; Jones, P. G. Organometallics 2012, 31, 1287.

http://dx.doi.org/10.1021/om2009588

 

Insertion of benzyne into the Pd-C bond. Synthesis of unnatural amino acid derivatives by sequential insertion of benzyne and CO: 2,2 ‘-functionalized biaryls containing alkylamino and carboxymethyl substituents. Isolation of stable carbopalladated-benzyne intermediates

García-López, J. A.; Oliva-Madrid, M. J.; Saura-Llamas, I.; Bautista, D.; Vicente, J. Chem. Commun. 2012, 48, 6744.

http://dx.doi.org/10.1039/c2cc32975a

 

A systematic study on the synthesis, reactivity and structure of ortho-palladated aryloximes, including the first cyclopalladated aryloximato and iminoaryloxime complexes

Vicente, J.; Chicote, M. T.; Abellán-López, A.; Bautista, D. Dalton Trans. 2012, 41, 752.

http://dx.doi.org/10.1039/c1dt11445j