2001 – 2005 | Grupo de Química Organometálica

Gold(I) complexes derived from C6Me3(C CH)(3)-1,3,5,C6Me4(C CH)(2)-1,4, and MeC6H4C CH-4

Vicente, J.; Chicote, M. T.; Álvarez-Falcón, M. M.; Jones, P. G. Organometallics 2005, 24, 5956.

http://dx.doi.org/10.1021/om050665f

Regiospecific functionalization of pharmaceuticals and other biologically active molecules through cyclopalladated compounds. 2-iodination of phentermine and L-tryptophan methyl ester

Vicente, J.; Saura-Llamas, I.; Bautista, D. Organometallics 2005, 24, 6001.

http://dx.doi.org/10.1021/om0506522

Synthesis and reactivity of trifluoromethyl isocyanide rhodium(I) complexes

Vicente, J.; Gil-Rubio, J.; Guerrero-Leal, J.; Bautista, D. Organometallics 2005, 24, 5634.

http://dx.doi.org/10.1021/om050573q

Synthesis and reactivity of ortho-palladated arylureas. Synthesis and catalytic activity of a C,N,C pincer complex. Stoichiometric syntheses of some N-heterocycles

Vicente, J.; Abad, J. A.; López-Serrano, J.; Jones, P. G.; Najera, C.; Botella-Segura, L. Organometallics 2005, 24, 5044.

http://dx.doi.org/10.1021/om050451y

(Fluoren-9-ylidene)methanedithiolato complexes of platinum: Synthesis, reactivity, and luminescence

Vicente, J.; González-Herrero, P.; Perez-Cadenas, M.; Jones, P. G.; Bautista, D. Inorg. Chem. 2005, 44, 7200.

http://dx.doi.org/10.1021/ic050748o

Metal-assisted aldol-type condensation of two acetimino ligands to give a 4-imino-2-methylpentan-2-amino rhodium(III) complex

Vicente, J.; Chicote, M. T.; Guerrero, R.; Vicente-Hernández, I.; Álvarez-Falcón, M. A.; Jones, P. G.; Bautista, D. Organometallics 2005, 24, 4506.

http://dx.doi.org/10.1021/om050553o

Gold(I) and silver(I)/gold(I) complexes derived from C6Me4(C CH)(2)-1,2

Vicente, J.; Chicote, M. T.; Álvarez-Falcón, M. M.; Jones, P. G. Organometallics 2005, 24, 4666.

http://dx.doi.org/10.1021/om050418b

A new approach to the synthesis of oligomers. Application to the synthesis of p-phenylene thioether wires

Vicente, J.; Abad, J. A.; López-Nicolas, R. M. Tetrahedron Letters 2005, 46, 5839.

http://dx.doi.org/10.1016/j.tetlet.2005.06.143

Synthesis, characterization, and metal complexes of polyacetylenes with pendant 2,2 ‘-bipyridyl groups

Vicente, J.; Gil-Rubio, J.; Barquero, N. Journal of Polymer Science Part a-Polymer Chemistry 2005, 43, 3167.

http://dx.doi.org/10.1002/pola.20816

Aqua palladium complexes: synthesis, properties and applications

Vicente, J.; Arcas, A. Coordination Chemistry Reviews 2005, 249, 1135.

http://dx.doi.org/10.1016/j.ccr.2004.11.005

Platinum(II) and mixed platinum(II)/gold(I) sigma-alkynyl complexes. The first anionic sigma-alkynyl metal polymers

Vicente, J.; Chicote, M. T.; Álvarez-Falcón, M. M.; Jones, P. G. Organometallics 2005, 24, 2764.

http://dx.doi.org/10.1021/om0501273

Reactivity of Pd{CH2C(O)Me}Cl (n) toward isocyanides

Vicente, J.; Arcas, A.; Fernández-Hernández, J. M.; Bautista, D.; Jones, P. G. Organometallics 2005, 24, 2516.

http://dx.doi.org/10.1021/om048999c

Reactivity of ortho-palladated phenol derivatives with unsaturated molecules: Insertion of nitriles into a late-transition-metal-carbon bond

Vicente, J.; Bad, J. A.; López-Sáez, M. J.; Jones, P. G. Angew. Chem. Int. Ed. 2005, 44, 6001.

http://dx.doi.org/10.1002/anie.200501202

An unprecedented process involving normal and redox transmetallation reactions between Hg and Pt affording the unexpected K Pt-2{CH2C(O)Me}(6)(mu-Cl)(3) complex: the key role of X-ray powder diffraction in unravelling its nature and structure

Vicente, J.; Arcas, A.; Fernández-Hernández, J. M.; Sironi, A.; Masciocchi, N. Chem. Commun. 2005, 1267.

http://dx.doi.org/10.1039/b416261g

The first metal complexes derived from 3,5-diethynylpyridine. X-ray crystal structure of (AuPTo(3))(2){mu-(C equivalent to C)(2)Py} (Py = pyridine-3,5-diyl; To = p-Tolyl)

Vicente, J.; Chicote, M. T.; Álvarez-Falcón, M. M.; Bautista, D. Organometallics 2004, 23, 5707.

http://dx.doi.org/10.1021/bm049509j

9H-fluorene-9-carbodithioic acids and dithioates. First isolation and characterization of a gem-enedithiol

Vicente, J.; González-Herrero, P.; García-Sánchez, Y.; Pérez-Cadenas, M. Tetrahedron Letters 2004, 45, 8859.

http://dx.doi.org/10.1016/j.tetlet.2004.09.180

(Fluoren-9-ylidene)methanedithiolato complexes of gold: Synthesis, luminescence, and charge-transfer adducts

Vicente, J.; González-Herrero, P.; García-Sánchez, Y.; Jones, P. G.; Bardají, M. Inorg. Chem. 2004, 43, 7516.

http://dx.doi.org/10.1021/ic049132+

Synthesis of the first family of rhodium(I) perfluoroalkyl complexes from rhodium(I) fluoro complexes

Vicente, J.; Gil-Rubio, J.; Guerrero-Leal, J.; Bautista, D. Organometallics 2004, 23, 4871.

http://dx.doi.org/10.1021/om049592a

Synthesis and reactivity of ortho-palladated arylcarbodiimides and aryl isothiocyanates. Formation of C-palladated quinazolines. Synthesis of 2-aminoquinolines

Vicente, J.; Abad, J.; López-Serrano, J.; Jones, P. G. Organometallics 2004, 23, 4711.

http://dx.doi.org/10.1021/om049580p

Reactivity of ortho-palladated phenol derivatives with unsaturated molecules. 1. Insertion of CO, isocyanides, alkenes, and alkynes. CO/alkene, alkyne/isocyanide, and isocyanide/alkene sequential insertion reactions

Vicente, J.; Abad, J. A.; Fortsch, W.; López-Sáez, M. J.; Jones, P. G. Organometallics 2004, 23, 4414.

http://dx.doi.org/10.1021/om0496131

Synthesis and reactivity of fluoro complexes: Part 2. Rhodium(I) fluoro complexes with alkene and phosphine ligands. Synthesis of the first isolated rhodium(I) bifluoride complexes. Structure of Rh-3(mu(3)-OH)(2)(COD)(3) (HF2) by X-ray powder diffraction

Vicente, J.; Gil-Rubio, J.; Bautista, D.; Sironi, A.; Masciocchi, N. Inorg. Chem. 2004, 43, 5665.

http://dx.doi.org/10.1021/ic049585e

Unexpected formation of an ortho-palladated diphenylthioether

Vicente, J.; Abad, J. A.; López-Nicolas, R. M.; Jones, P. G. Organometallics 2004, 23, 4325.

http://dx.doi.org/10.1021/om0496683

Bis(2,6-dinitroaryl)platinum complexes. 1. Synthesis through transmetalation reactions

Vicente, J.; Arcas, A.; Galvez-López, M. D.; Jones, P. G. Organometallics 2004, 23, 3521.

http://dx.doi.org/10.1021/om049801r

Bis(2,6-dinitroaryl)platinum complexes. 2. Di- and trinuclear complexes containing Pt-Hg bonds

Vicente, J.; Arcas, A.; Galvez-López, M. D.; Jones, P. G. Organometallics 2004, 23, 3528.

http://dx.doi.org/10.1021/om049699y

Synthesis and reactivity of ortho-mercuriated and ortho-palladated arylacetals and cyclic and acyclic aryldithioacetals. New examples of the rearrangement of acyclic dithioacetal aryl- to dithioether alkyl-palladium complexes

Vicente, J.; Abad, J. A.; Hernández-Mata, F. S.; Rink, B.; Jones, P. G.; de Arellano, M. C. R. Organometallics 2004, 23, 1292.

http://dx.doi.org/10.1021/om0342964

Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle

Vicente, J.; Chicote, M. T.; Álvarez-Falcón, M. M.; Jones, P. G. Chem. Commun. 2004, 2658.

http://dx.doi.org/10.1039/b409921d

Ortho-metalated primary amines. 6. The first synthesis of six-membered palladacycles from primary amines containing electron-withdrawing substituents: End of the limiting rules of Cope and Friedrich on cyclopalladation of benzyl- and phenethylamines

Vicente, J.; Saura-Llamas, I.; Cuadrado, J.; de Arellano, M. C. R. Organometallics 2003, 22, 5513.

http://dx.doi.org/10.1021/om030480d

Synthesis of Ag(NH=CMe2)(2) ClO4 and its use as a source of acetimine. 1. Synthesis of the first acetimine rhodium complexes and the first crystal structure of a diacetonamine complex

Vicente, J.; Chicote, M. T.; Guerrero, R.; Vicente-Hernández, I.; Jones, P. G. Inorg. Chem. 2003, 42, 7644.

http://dx.doi.org/10.1021/ic035002+

Alkynyl gold(I) rigid-rod molecules from 1,12-bis(ethynyl)-1,12-dicarba-closo-dodecaborane(12)

Vicente, J.; Chicote, M. T.; Álvarez-Falcón, M. M.; Fox, M. A.; Bautista, D. Organometallics 2003, 22, 4792.

http://dx.doi.org/10.1021/om0304311

Mercurated and palladated iminophosphoranes. Synthesis and reactivity

Vicente, J.; Abad, J. A.; Clemente, R.; López-Serrano, J.; de Arellano, M. C. R.; Jones, P. G.; Bautista, D. Organometallics 2003, 22, 4248.

http://dx.doi.org/10.1021/om0303552

New carbenegold(I) complexes synthesized by the “acac method”

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; Álvarez-Falcón, M. M.; de Arellano, M. C. R.; Jones, P. G. Organometallics 2003, 22, 4327.

http://dx.doi.org/10.1021/om030372r

1,1-ethylenedithiolato complexes of palladium(II) and platinum(II) with isocyanide and carbene ligands

Vicente, J.; Chicote, M. T.; Huertas, S.; Jones, P. G. Inorg. Chem. 2003, 42, 4268.

http://dx.doi.org/10.1021/ic0343758

Nucleophilic attack of carbonyl-stabilized phosphorus ylides on neutral and cationic alkene platinum(II) complexes

Vicente, J.; Chicote, M. T.; MacBeath, C.; Jones, P. G. Organometallics 2003, 22, 1843.

http://dx.doi.org/10.1021/om020970q

Depalladation reactions of iminoacyl- and 2-acetylarylpalladium(II) complexes

Vicente, J.; Abad, J. A.; Martínez-Viviente, E.; Jones, P. G. Organometallics 2003, 22, 1967.

http://dx.doi.org/10.1021/om030045j

New arenediethynylgold(I) complexes. Crystal structures of Ph3PAuC C(phenylendiyl-1,3)C CAuPPh3 and Ph3PAuC C(mesitylendiyl-1,3)C CAuPPh3

Vicente, J.; Chicote, M. T.; Álvarez-Falcón, M. M.; Abrisqueta, M. D.; Hernández, F. J.; Jones, P. G. Inorganica Chimica Acta 2003, 347, 67.

http://dx.doi.org/10.1016/s0020-1693(02)01443-3

New ylide-, alkynyl-, and mixed alkyny/ylide-gold(I) complexes

Vicente, J.; Singhal, A. R.; Jones, P. G. Organometallics 2002, 21, 5887.

http://dx.doi.org/10.1021/om020753p

The first anionic arenediethynylgold(I) complexes

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; Álvarez-Falcón, M. M. J. Organomet. Chem. 2002, 663, 40.

http://dx.doi.org/10.1016/s0022-328x(02)01621-2

Mono- and di-nuclear complexes of ortho-palladated and -platinated 4,4 ‘-dimethylazobenzene with bis(diphenylphosphino)methane. More data on transphobia

Vicente, J.; Arcas, A.; Bautista, D.; de Arellano, M. C. R. J. Organomet. Chem. 2002, 663, 164.

http://dx.doi.org/10.1016/s0022-328x(02)01729-1

Study of the reactivity of 2-acetyl-, 2-cyano-, 2-formyl-, and 2-vinylphenyl palladium(II) complexes. Mono- and triinsertion of an isocyanide into the Pd-C bond. A 2-cyanophenyl palladium complex as a ligand

Vicente, J.; Abad, J. A.; Martínez-Viviente, E.; Jones, P. G. Organometallics 2002, 21, 4454.

http://dx.doi.org/10.1021/om020380s

Synthesis of the first family of platinum(IV) complexes with phosphorus ylide ligands

Bokach, N. A.; Selivanov, S. I.; Kukushkin, V. Y.; Vicente, J.; Haukka, M.; Pombeiro, A. J. L. Organometallics 2002, 21, 3744.

http://dx.doi.org/10.1021/om020113m

Palladium-assisted formation of carbon-carbon bonds. Part 10. Insertion reactions of isocyanides into the Pd-C bond of orthopalladated primary amines. Synthesis of 2-R-aminoisoindolinium salts (R = Bu-t, 2,6-xylyl)

Vicente, J.; Saura-Llamas, I.; Grunwald, C.; Alcaraz, C.; Jones, P. G.; Bautista, D. Organometallics 2002, 21, 3587.

http://dx.doi.org/10.1021/om020365n

An unusual palladium complex involved in an unusual rearrangement of ortho-palladated aryldithioacetals

Vicente, J.; Abad, J. A.; Hernández-Mata, F. S.; Jones, P. G. J. Am. Chem. Soc. 2002, 124, 3848.

http://dx.doi.org/10.1021/ja0175035

Synthesis of tris- and tetrakis(pyrazol-1-yl)borate gold(III) complexes. Crystal structures of Au{kappa(2)-N,N ‘-BH(Pz)(3)}Cl-2 (pz = pyrazol-1-yl) and Au{kappa(2)-N,N ‘-B(Pz)(4)} (kappa(2)-C,N-C6H4CH2NMe2-2) ClO4 center dot CHCl3

Vicente, J.; Chicote, M. T.; Guerrero, R.; Herber, U. Inorg. Chem. 2002, 41, 1870.

http://dx.doi.org/10.1021/ic011031d

5-Methylquinoxaline as a versatile mono-, bi- and tridentate ligand in Palladium(II) chemistry. Crystal structures of trans- Pd(OAc)(2)(N1-C8H5N2Me-5)(2) and Pd(OAc)(C,N4-CH2C8H5N2-5)(PPh3)

Vicente, J.; Lagunas, M. C.; Bleuel, E.; de Arellano, M. C. R. J. Organomet. Chem. 2002, 648, 62.

http://dx.doi.org/10.1016/s0022-328x(01)01394-8

Synthesis and reactivity toward isonitriles of (2-aminoaryl)palladium(II) complexes

Vicente, J.; Abad, J. A.; Frankland, A. D.; López-Serrano, J.; de Arellano, M. C. R.; Jones, P. G. Organometallics 2002, 21, 272.

http://dx.doi.org/10.1021/om0104971

Synthesis and Reactivity toward alkynes of 2-formyl- and 2-acetylarylpalladium(II) (aryl = phenyl and 5-nitrophenyl) complexes. Formation of Indenols and Indenones

Vicente, J.; Abad, J. A.; López-Peláez, B.; Martínez-Viviente, E. Organometallics 2002, 21, 58.

http://dx.doi.org/10.1021/om010710t

Heterodi- MAg, MAu (M = Pd, Pt) , tri- PdAg2, PtAg2, PtAu2, Pt2M (M = Ni, Pt, Cd, Hg) , and tetranuclear (Pt2Ag2, Pt2Au2) 1,1-ethylenedithiolato complexes

Vicente, J.; Chicote, M. T.; Huertas, S.; Jones, P. G.; Fischer, A. K. Inorg. Chem. 2001, 40, 6193.

http://dx.doi.org/10.1021/ic010488k

Polymetalated aromatic compounds. 1. Synthesis of mono-, di-, and tripalladated mesitylene derivatives

Vicente, J.; Lyakhovych, M.; Bautista, D.; Jones, P. G. Organometallics 2001, 20, 4695.

http://dx.doi.org/10.1021/om0105472

Synthesis of ortho-palladated phenol derivatives. Study of their reactivity with carbon monoxide and isonitriles

Vicente, J.; Abad, J. A.; Fortsch, W.; Jones, P. G.; Fischer, A. K. Organometallics 2001, 20, 2704.

http://dx.doi.org/10.1021/om010074z

Pd{CH2C(O)Me}Cl n, a key product for the synthesis of acetonylpalladium(II) complexes

Vicente, J.; Arcas, A.; Fernández-Hernández, J. M.; Bautista, D. Organometallics 2001, 20, 2767.

http://dx.doi.org/10.1021/om0101036

Synthesis and reactivity of fluoro complexes. Part 1. Cyclooctadiene rhodium(I) complexes

Vicente, J.; Gil-Rubio, J.; Bautista, D. Inorg. Chem. 2001, 40, 2636.

http://dx.doi.org/10.1021/ic015526e

Mononuclear (Pd, Pt), heterodinuclear (PdAg, PtAg), and tetranuclear (Pd2Ag2, Pf(2)Ag(2)) 1,1-ethylenedithiolato complexes

Vicente, J.; Chicote, M. T.; Huertas, S.; Bautista, D.; Jones, P. G.; Fischer, A. K. Inorg. Chem. 2001, 40, 2051.

http://dx.doi.org/10.1021/ic000996e

Reduction of (imine)Pt(IV) to (imine)Pt(II) complexes with carbonyl-stabilized phosphorus ylides

Wagner, G.; Pakhomova, T. B.; Bokach, N. A.; da Siva, J.; Vicente, J.; Pombeiro, A. J. L.; Kukushkin, V. Y. Inorg. Chem. 2001, 40, 1683.

http://dx.doi.org/10.1021/ic000769c

Syntheses of palladated aryldithioacetals. Unexpected rearrangement involving C-S and C-Pd bonds

Vicente, J.; Abad, J. A.; Hernández-Mata, F. S.; Jones, P. G. Organometallics 2001, 20, 1109.

http://dx.doi.org/10.1021/om0008981

Gold complexes with N donor ligands, part 4 – The first acetimine gold(I) and gold(III) complexes and the first acetonine complexes

Vicente, J.; Chicote, M. T.; Guerrero, R.; Saura-Llamas, I. M.; Jones, P. G.; de Arellano, M. C. R. Chem. Eur. J. 2001, 7, 638.

http://dx.doi.org/10.1002/1521-3765(20010202)7:3<638::aid-chem638>3.0.co;2-a